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Energy

In physics, energy is a quantity that is often understood as the ability to perform work. This quantity can be assigned to any particle, object, or system of objects as a consequence of its physical state.

Different forms of energy include kinetic, potential, thermal, gravitational, sound, elastic and electromagnetic energy. The forms of energy are often named after a related force. German physicist Hermann von Helmholtz established that all forms of energy are equivalent — energy in one form can disappear but the same amount of energy will appear in another form. A restatement of this idea is that energy is subject to a conservation law over time.

Any form of energy can be transformed into another form. When energy is in a form other than thermal energy, it may be transformed with good or even perfect efficiency, to any other type of energy. With thermal energy, however, there are often limits to the efficiency of the conversion to other forms of energy, due to the second law of thermodynamics. As an example, when oil reacts with oxygen, potential energy is released, since new chemical bonds are formed in the products which are more stable than those in the oil and oxygen. The released energy resulting from this process may be converted directly to electricity (as in a fuel cell) with good efficiency. Alternately it may be converted into thermal energy if the oil is simply burned. In the latter case, however, some of the thermal energy can no longer be used to perform work at that temperature, and is said to be "degraded." As such, it exists in a form unavailable for further transformation. The remainder of the thermal energy may be used to produce any other type of energy, such as electricity.

In all such energy transformation processes, the total energy remains the same. Energy may not be created nor destroyed. This principle, the conservation of energy, was first postulated in the early 19th century, and applies to any isolated system. According to Noether's theorem, the conservation of energy is a consequence of the fact that the laws of physics do not change over time.

Although the total energy of a system does not change with time, its value may depend on the frame of reference. For example, a seated passenger in a moving airplane has zero kinetic energy relative to the airplane, but non-zero kinetic energy (and higher total energy) relative to the Earth.

Energy is a scalar physical quantity. In the International System of Units (SI), energy is measured in joules, but in some fields other units such as kilowatt-hours and kilocalories are also used.

Conservation of energy

Energy is subject to the law of conservation of energy. According to this law, energy can neither be created (produced) nor destroyed by itself. It can only be transformed.

Most kinds of energy (with gravitational energy being a notable exception) are also subject to strict local conservation laws, as well. In this case, energy can only be exchanged between adjacent regions of space, and all observers agree as to the volumetric density of energy in any given space. There is also a global law of conservation of energy, stating that the total energy of the universe cannot change; this is a corollary of the local law, but not vice versa^. Conservation of energy is the mathematical consequence of translational symmetry of time (that is, the indistinguishability of time intervals taken at different time) - see Noether's theorem.

According to energy conservation law the total inflow of energy into a system must equal the total outflow of energy from the system, plus the change in the energy contained within the system.

This law is a fundamental principle of physics. It follows from the translational symmetry of time, a property of most phenomena below the cosmic scale that makes them independent of their locations on the time coordinate. Put differently, yesterday, today, and tomorrow are physically indistinguishable.

This is because energy is the quantity which is canonical conjugate to time. This mathematical entanglement of energy and time also results in the uncertainty principle - it is impossible to define the exact amount of energy during any definite time interval. The uncertainty principle should not be confused with energy conservation - rather it provides mathematical limits to which energy can in principle be defined and measured.

In quantum mechanics energy is expressed using the Hamiltonian operator. On any time scales, the uncertainty in the energy is by

$\Delta E \Delta t \ge \frac { \hbar } {2 }$

which is similar in form to the Heisenberg uncertainty principle (but not really mathematically equivalent thereto, since H and t are not dynamically conjugate variables, neither in classical nor in quantum mechanics).

In particle physics, this inequality permits a qualitative understanding of virtual particles which carry momentum, exchange by which and with real particles, is responsible for the creation of all known fundamental forces (more accurately known as fundamental interactions). Virtual photons (which are simply lowest quantum mechanical energy state of photons) are also responsible for electrostatic interaction between electric charges (which results in Coulomb law), for spontaneous radiative decay of exited atomic and nuclear states, for the Casimir force, for van der Waals bond forces and some other observable phenomena.

Applications of the concept of energy

Energy is subject to a strict global conservation law; that is, whenever one measures (or calculates) the total energy of a system of particles whose interactions do not depend explicitly on time, it is found that the total energy of the system always remains constant.

The total energy of a system can be subdivided and classified in various ways. For example, it is sometimes convenient to distinguish potential energy (which is a function of coordinates only) from kinetic energy (which is a function of coordinate time derivatives only). It may also be convenient to distinguish gravitational energy, electric energy, thermal energy, and other forms. These classifications overlap; for instance, thermal energy usually consists partly of kinetic and partly of potential energy.
The transfer of energy can take various forms; familiar examples include work, heat flow, and advection, as discussed below.
The word "energy" is also used outside of physics in many ways, which can lead to ambiguity and inconsistency. The vernacular terminology is not consistent with technical terminology. For example, while energy is always conserved (in the sense that the total energy does not change despite energy transformations), energy can be converted into a form, e.g., thermal energy, that cannot be utilized to perform work. When one talks about "conserving energy by driving less," one talks about conserving fossil fuels and preventing useful energy from being lost as heat. This usage of "conserve" differs from that of the law of conservation of energy.

In classical physics energy is considered a scalar quantity, the canonical conjugate to time. In special relativity energy is also a scalar (although not a Lorentz scalar but a time component of the energy-momentum 4-vector).In other words, energy is invariant with respect to rotations of space, but not invariant with respect to rotations of space-time (= boosts).

Energy transfer

Because energy is strictly conserved and is also locally conserved (wherever it can be defined), it is important to remember that by the definition of energy the transfer of energy between the "system" and adjacent regions is work. A familiar example is mechanical work. In simple cases this is written as the following equation:

Δ E = W

if there are no other energy-transfer processes involved. Here

E

is the amount of energy transferred, and

W

represents the work done on the system.

More generally, the energy transfer can be split into two categories:

Δ E = W + Q

where

Q

represents the heat flow into the system.

There are other ways in which an open system can gain or lose energy. In chemical systems, energy can be added to a system by means of adding substances with different chemical potentials, which potentials are then extracted (both of these process are illustrated by fueling an auto, a system which gains in energy thereby, without addition of either work or heat). Winding a clock would be adding energy to a mechanical system. These terms may be added to the above equation, or they can generally be subsumed into a quantity called "energy addition term

E

" which refers to any type of energy carried over the surface of a control volume or system volume. Examples may be seen above, and many others can be imagined (for example, the kinetic energy of a stream of particles entering a system, or energy from a laser beam adds to system energy, without either being either work-done or heat-added, in the classic senses).

Δ E = W + Q + E

Where E in this general equation represents other additional advected energy terms not covered by work done on a system, or heat added to it.

Energy is also transferred from potential energy (

E p

) to kinetic energy (

E k

) and then back to potential energy constantly. This is referred to as conservation of energy. In this closed system, energy cannot be created or destroyed; therefore, the initial energy and the final energy will be equal to each other. This can be demonstrated by the following:

E p i + E k i = E p F + E k F

The equation can then be simplified further since

E p = m g h

(mass times acceleration due to gravity times the height) and $E_k = \frac{1}{2} mv^2$ (half mass times velocity squared). Then the total amount of energy can be found by adding

E p + E k = E t o t a l

Energy and the laws of motion

In classical mechanics, energy is a conceptually and mathematically useful property, as it is a conserved quantity. Several formulations of mechanics have been developed using energy as a core concept.

The Hamiltonian

The total energy of a system is sometimes called the Hamiltonian, after William Rowan Hamilton. The classical equations of motion can be written in terms of the Hamiltonian, even for highly complex or abstract systems. These classical equations have remarkably direct analogs in nonrelativistic quantum mechanics.

The Lagrangian

Another energy-related concept is called the Lagrangian, after Joseph Louis Lagrange. This is even more fundamental than the Hamiltonian, and can be used to derive the equations of motion. It was invented in the context of classical mechanics, but is generally useful in modern physics. The Lagrangian is defined as the kinetic energy minus the potential energy.

Usually, the Lagrange formalism is mathematically more convenient than the Hamiltonian for non-conservative systems (such as systems with friction).

Energy and thermodynamics

Internal energy

Internal energy is the sum of all microscopic forms of energy of a system. It is the energy needed to create the system. It is related to the potential energy, e.g., molecular structure, crystal structure, and other geometric aspects, as well as the motion of the particles, in form of kinetic energy. Thermodynamics is chiefly concerned with changes in internal energy and not its absolute value, which is impossible to determine with thermodynamics alone.

The laws of thermodynamics

According to the second law of thermodynamics, work can be totally converted into heat, but not vice versa. This is a mathematical consequence of statistical mechanics. The first law of thermodynamics simply asserts that energy is conserved, and that heat is included as a form of energy transfer. A commonly used corollary of the first law is that for a "system" subject only to pressure forces and heat transfer (e.g., a cylinder-full of gas), the differential change in energy of the system (with a gain in energy signified by a positive quantity) is given as the following equation:

$\mathrm{d}E = T\mathrm{d}S - P\mathrm{d}V\,$ ,

where the first term on the right is the heat transfer into the system, defined in terms of temperature T and entropy S (in which entropy increases and the change dS is positive when the system is heated), and the last term on the right hand side is identified as "work" done on the system, where pressure is P and volume V (the negative sign results since compression of the system requires work to be done on it and so the volume change, dV, is negative when work is done on the system). Although this equation is the standard textbook example of energy conservation in classical thermodynamics, it is highly specific, ignoring all chemical, electric, nuclear, and gravitational forces, effects such as advection of any form of energy other than heat, and because it contains a term that depends on temperature. The most general statement of the first law (i.e., conservation of energy) is valid even in situations in which temperature is undefinable.

Energy is sometimes expressed as the following equation:

$\mathrm{d}E=\delta Q+\delta W\,$ ,

which is unsatisfactory because there cannot exist any thermodynamic state functions W or Q that are meaningful on the right hand side of this equation, except perhaps in trivial cases.

Equipartition of energy

The energy of a mechanical harmonic oscillator (a mass on a spring) is alternatively kinetic and potential. At two points in the oscillation cycle it is entirely kinetic, and alternatively at two other points it is entirely potential. Over the whole cycle, or over many cycles, net energy is thus equally split between kinetic and potential. This is called equipartition principle; total energy of a system with many degrees of freedom is equally split among all available degrees of freedom.

This principle is vitally important to understanding the behavior of a quantity closely related to energy, called entropy. Entropy is a measure of evenness of a distribution of energy between parts of a system. When an isolated system is given more degrees of freedom (i.e., given new available energy states that are the same as existing states), then total energy spreads over all available degrees equally without distinction between "new" and "old" degrees. This mathematical result is called the second law of thermodynamics.

Forms of energy

Mechanical energy

Mechanical energy manifest in many forms,but can be broadly classified into elastic potential energy and kinetic energy. The term potential energy is a very general term, because it exists in all force fields, such as gravitation, electrostatic and magnetic fields. Potential energy refers to the energy any object gets due to its position in a force field.

Main article: Potential energy

Potential energy, symbols E_p, V or Φ, is defined as the work done against a given force (= work of given force with minus sign) in changing the position of an object with respect to a reference position (often taken to be infinite separation). If F is the force and s is the displacement,

$E_{\rm p} = -\int \mathbf{F}\cdot{\rm d}\mathbf{s}$

with the dot representing the scalar product of the two vectors.

The name "potential" energy originally signified the idea that the energy could readily be transferred as work—at least in an idealized system (reversible process, see below). This is not completely true for any real system, but is often a reasonable first approximation in classical mechanics.

The general equation above can be simplified in a number of common cases, notably when dealing with gravity or with elastic forces.

Elastic potential energy

As a ball falls freely under the influence of gravity, it accelerates downward, its initial potential energy converting into kinetic energy. On impact with a hard surface the ball deforms, converting the kinetic energy into elastic potential energy. As the ball springs back, the energy converts back firstly to kinetic energy and then as the ball re-gains height into potential energy. Energy conversion to heat due to inelastic deformation and air resistance cause each successive bounce to be lower than the last.

Main article: Elastic potential energy

Elastic potential energy is defined as a work needed to compress (or expand) a spring. The force, F, in a spring or any other system which obeys Hooke's law is proportional to the extension or compression, x,

F = - k x

where k is the force constant of the particular spring (or system). In this case, the calculated work becomes

$E_{\rm p,e} = {1\over 2}kx^2$

only when k is constant. Hooke's law is a good approximation for behaviour of chemical bonds under normal conditions, i.e. when they are not being broken or formed.

Kinetic energy

Main article: Kinetic energy

Kinetic energy, symbols E_k, T or K, is the work required to accelerate an object to a given speed. Indeed, calculating this work one easily obtains the following:

$E_{\rm k} = \int \mathbf{F} \cdot d \mathbf{x} = \int \mathbf{v} \cdot d \mathbf{p}= {1\over 2}mv^2$

At speeds approaching the speed of light, c, this work must be calculated using Lorentz transformations, which results in the following:

$E_{\rm k} = m c^2\left(\frac{1}{\sqrt{1 - (v/c)^2}} - 1\right)$

Here the two terms on the right hand side are identified with the total energy and the rest energy of the object, respectively. This equation reduces to the one above it, at small (compared to c) speed. The kinetic energy is zero at v=0, so that at rest, the total energy is the rest energy. Thus, a resting mass has the amount of total energy equal to:

E rest = m c 2

This energy is thus called rest mass energy.

[edit] Surface energy

If there is any kind of tension in a surface, such as a stretched sheet of rubber or material interfaces, it is possible to define surface energy. In particular, any meeting of dissimilar materials that don't mix will result in some kind of surface tension, if there is freedom for the surfaces to move then, as seen in capillary surfaces for example, the minimum energy will as usual be sought.

A minimal surface, for example, represents the smallest possible energy that a surface can have if its energy is proportional to the area of the surface. For this reason, (open) soap films of small size are minimal surfaces (small size reduces gravity effects, and openness prevents pressure from building up. Note that a bubble is a minimum energy surface but not a minimal surface by definition).

Sound energy

Sound is a form of mechanical vibration, which propagates through any mechanical medium. It is closely related to the ability of the human ear to perceive sound. The wide outer area of the ear is maximized to collect sound vibrations. It is amplified and passed through the outer ear, striking the eardrum, which transmits sounds into the inner ear. Auditory nerves fire according to the particular vibrations of the sound waves in the inner ear, which designate such things as the pitch and volume of the sound. The ear is set up in an optimal way to interpret sound energy in the form of vibrations.

Gravitational energy

Main article: Gravitational potential energy

The gravitational force near the Earth's surface varies very little with the height, h, and is equal to the mass, m, multiplied by the gravitational acceleration, g = 9.81 m/s². In these cases, the gravitational potential energy is given by

E p,g = m g h

A more general expression for the potential energy due to Newtonian gravitation between two bodies of masses m₁ and m₂, useful in astronomy, is

$E_{\rm p,g} = -G{{m_1m_2}\over{r}}$ ,

where r is the separation between the two bodies and G is the gravitational constant, 6.6742(10)×10⁻¹¹ m³kg⁻¹s⁻² In this case, the reference point is the infinite separation of the two bodies.

Thermal energy

Main article: Thermal energy

Thermal energy (of some media - gas, plasma, solid, etc.) is the energy associated with the microscopical random motion of particles constituting the media. For example, in case of monoatomic gas it is just a kinetic energy of motion of atoms of gas as measured in the reference frame of the center of mass of gas. In case of molecules in the gas rotational and vibrational energy is involved. In the case of liquids and solids there is also potential energy (of interaction of atoms) involved, and so on.

A heat is defined as a transfer (flow) of thermal energy across certain boundary (for example, from a hot body to cold via the area of their contact. A practical definition for small transfers of heat is

$\Delta q = \int C_{\rm v}{\rm d}T$

where C_v is the heat capacity of the system. This definition will fail if the system undergoes a phase transition—e.g. if ice is melting to water—as in these cases the system can absorb heat without increasing its temperature. In more complex systems, it is preferable to use the concept of internal energy rather than that of thermal energy (see Chemical energy below).

Despite the theoretical problems, the above definition is useful in the experimental measurement of energy changes. In a wide variety of situations, it is possible to use the energy released by a system to raise the temperature of another object, e.g. a bath of water. It is also possible to measure the amount of electric energy required to raise the temperature of the object by the same amount. The calorie was originally defined as the amount of energy required to raise the temperature of one gram of water by 1 °C (approximately 4.1855 J, although the definition later changed), and the British thermal unit was defined as the energy required to heat one pound of water by 1 °F (later fixed as 1055.06 J).

Electric energy

Electrostatic energy

The electric potential energy of given configuration of charges is defined as the work which must be done against the Coulomb force to rearrange charges from infinite separation to this configuration (or the work done by the Coulomb force separating the charges from this configuration to infinity). For two point-like charges Q₁ and Q₂ at a distance r this work, and hence electric potential energy is equal to:

$E_{\rm p,e} = {1\over {4\pi\epsilon_0}}{{Q_1Q_2}\over{r}}$

where ε₀ is the electric constant of a vacuum, 10⁷/4πc₀² or 8.854188…×10⁻¹² F/m.^[22] If the charge is accumulated in a capacitor (of capacitance C), the reference configuration is usually selected not to be infinite separation of charges, but vice versa - charges at an extremely close proximity to each other (so there is zero net charge on each plate of a capacitor). The justification for this choice is purely practical - it is easier to measure both voltage difference and magnitude of charges on a capacitor plates not versus infinite separation of charges but rather versus discharged capacitor where charges return to close proximity to each other (electrons and ions recombine making the plates neutral). In this case the work and thus the electric potential energy becomes.

Electricity energy

If an electric current passes through a resistor, electric energy is converted to heat; if the current passes through an electric appliance, some of the electric energy will be converted into other forms of energy (although some will always be lost as heat). The amount of electric energy due to an electric current can be expressed in a number of different ways:

$E = UQ = UIt = Pt = {{U^2}{t}\over{R}} = {I^2}Rt$

where U is the electric potential difference (in volts), Q is the charge (in coulombs), I is the current (in amperes), t is the time for which the current flows (in seconds), P is the power (in watts) and R is the electric resistance (in ohms). The last of these expressions is important in the practical measurement of energy, as potential difference, resistance and time can all be measured with considerable accuracy.

Magnetic energy

There is no fundamental difference between magnetic energy and electric energy: the two phenomena are related by Maxwell's equations. The potential energy of a magnet of magnetic moment m in a magnetic field B is defined as the work of magnetic force (actually of magnetic torque) on re-alignment of the vector of the magnetic dipole moment, and is equal:

$E_{\rm p,m} = -m\cdot B$

while the energy stored in an inductor (of inductance L) when current I is passing via it is

$E_{\rm p,m} = {1\over 2}LI^2$ .

This second expression forms the basis for superconducting magnetic energy storage.

Electromagnetic Energy

Calculating work needed to create an electric or magnetic field in unit volume (say, in a capacitor or an inductor) results in the electric and magnetic fields energy densities:

$u_e=\frac{\epsilon_0}{2} E^2$

and

$u_m=\frac{1}{2\mu_0} B^2$ ,

in SI units.

Electromagnetic radiation, such as microwaves, visible light or gamma rays, represents a flow of electromagnetic energy. Applying the above expressions to magnetic and electric components of electromagnetic field both the

volumetric density and the flow of energy in e/m field can be calculated. The resulting Poynting vector, which is expressed as

$\mathbf{S} = \frac{1}{\mu} \mathbf{E} \times \mathbf{B},$

in SI units, gives the density of the flow of energy and its direction.

The energy of electromagnetic radiation is quantized (has discrete energy levels). The spacing between these levels is equal to

E = h ν

where h is the Planck constant, 6.6260693(11)×10⁻³⁴ Js, and ν is the frequency of the radiation. This quantity of electromagnetic energy is usually called a photon. The photons which make up visible light have energies of 270–520 yJ, equivalent to 160–310 kJ/mol, the strength of weaker chemical bonds.

Chemical energy

Main article: Chemical thermodynamics

Chemical energy is the energy due to associations of atoms in molecules and various other kinds of aggregates of matter. It may be defined as a work done by

electric forces during re-arrangement of mutual positions of electric charges, electrons and protons, in the process of aggregation. So, basically it is electrostatic potential energy of electric charges. If the chemical energy of a system decreases during a chemical reaction, the difference is transferred to the surroundings in some form (often heat or light); on the other hand if the chemical energy of a system increases as a result of a chemical reaction - the difference then is supplied by the surroundings (usually again in form of heat or light). For example,

when two hydrogen atoms react to form a dihydrogen molecule, the chemical energy decreases by 724 zJ (the bond energy of the H–H bond);

when the electron is completely removed from a hydrogen atom, forming a hydrogen ion (in the gas phase), the chemical energy increases by 2.18 aJ (the ionization energy of hydrogen).

It is common to quote the changes in chemical energy for one mole of the substance in question: typical values for the change in molar chemical energy during a chemical reaction range from tens to hundreds of kilojoules per mole.

The chemical energy as defined above is also referred to by chemists as the internal energy, U: technically, this is measured by keeping the volume of the system constant. Most practical chemistry is performed at constant pressure and, if the volume changes during the reaction (e.g. a gas is given off), a correction must be applied to take account of the work done by or on the atmosphere to obtain the enthalpy, H:

ΔH = ΔU + PΔV

A second correction, for the change in entropy, S, must also be performed to determine whether a chemical reaction will take place or not, giving the Gibbs free energy, G:

ΔG = ΔH − TΔS

These corrections are sometimes negligible, but often not (especially in reactions involving gases).

Since the industrial revolution, the burning of coal, oil, natural gas or products derived from them has been a socially significant transformation of chemical energy into other forms of energy. the energy "consumption" (one should really speak of "energy transformation") of a society or country is often quoted in reference to the average energy released by the combustion of these fossil fuels:

1 tonne of coal equivalent (TCE) = 29.3076 GJ = 8,141 kilowatt hour

1 tonne of oil equivalent (TOE) = 41.868 GJ = 11,630 kilowatt hour

On the same basis, a tank-full of gasoline (45 litres, 12 gallons) is equivalent to about 1.6 GJ of chemical energy. Another chemically based unit of measurement for energy is the "tonne of TNT", taken as 4.184 GJ. Hence, burning a tonne of oil releases about ten times as much energy as the explosion of one tonne of TNT: fortunately, the energy is usually released in a slower, more controlled manner.

Simple examples of storage of chemical energy are batteries and food. When food is digested and metabolized (often with oxygen), chemical energy is released, which can in turn be transformed into heat, or by muscles into kinetic energy.

Nuclear energy

Main article: Nuclear binding energy

Nuclear potential energy, along with electric potential energy, provides the energy released from nuclear fission and nuclear fusion processes. The result of both these processes are nuclei in which the more-optimal size of the nucleus allows the nuclear force (which is opposed by the electromagnetic force) to bind nuclear particles more tightly together than before the reaction.

The Weak nuclear force (different from the strong force) provides the potential energy for certain kinds of radioactive decay, such as beta decay.

The energy released in nuclear processes is so large that the relativistic change in mass (after the energy has been removed) can be as much as several parts per thousand.

Nuclear particles (nucleons) like protons and neutrons are not destroyed (law of conservation of baryon number) in fission and fusion processes. A few lighter particles may be created or destroyed (example: beta minus and beta plus decay, or electron capture decay), but these minor processes are not important to the immediate energy release in fission and fusion. Rather, fission and fusion release energy when collections of baryons become more tightly bound, and it is the energy associated with a fraction of the mass of the nucleons (but not the whole particles) which appears as the heat and electromagnetic radiation generated by nuclear reactions. This heat and radiation retains the "missing" mass, but the mass is missing only because it escapes in the form of heat or light, which retain the mass and conduct it out of the system where it is not measured.

The energy from the Sun, also called solar energy, is an example of this form of energy conversion. In the Sun, the process of hydrogen fusion converts about 4 million metric tons of solar matter per second into light, which is radiated into space, but during this process, the number of total protons and neutrons in the sun does not change. In this system, the light itself retains the inertial equivalent of this mass, and indeed the mass itself (as a system), which represents 4 million tons per second of electromagnetic radiation, moving into space. Each of the helium nuclei which are formed in the process are less massive than the four protons from they were formed, but (to a good approximation), no particles or atoms are destroyed in the process of turning the sun's nuclear potential energy into light.

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NEWbee blog

28 Oktober 2010

<^_^> energy <^_^>